Matching and measuring
Most of this diagram cannot be shown
The chromaticity horseshoe is the canonical illustration of colour science, and nearly every printed copy is filled edge to edge with colours the page cannot produce. The honest version marks them, and the marking covers most of the picture.
Matching is not appearance
CIE XYZ predicts when two lights will look the same under identical viewing conditions. It was never a model of how anything looks, and most of the confusion in applied colour comes from using it as one.
What a gamut costs
Three primaries reach a triangle and the visible region is not a triangle, so something has to give. Widening the primaries helps, has a price in precision and compatibility, and runs into a limit that is geometric rather than technological.
A hex code is not a colour
Six hexadecimal digits identify three numbers. Turning three numbers into a colour needs a colour space, a transfer function, a white point and a display, and leaving any of them unstated is the everyday version of every confusion on this site.