Colour Science & Perception
what the eye settles, and what it cannot
Concept

Refractive index — where it appears

How much a material slows and bends light, which varies with wavelength and is what makes a prism work. Its variation is why the eye cannot focus every wavelength at once and why the interface reflection is nearly flat across the visible band.

Named by 4 essays across one field — each of them below, with the objects they name alongside it.

A glossy surface returns two spectra, and only one of them is the paint. The dichromatic reflection model, computed rather than assumed. Light that enters a dielectric binder, scatters off pigment and comes back carries the reflectance — the body component, ΔE00 = 33.7 from the lamp. Light reflected at the interface never entered, so it carries the lamp's spectrum with only Fresnel's slight dispersion on it: ΔE00 = 1.06. The interface term is computed from Fresnel's equations on a Cauchy index at 55°, so its near-neutrality is a result here rather than an assumption. This is why a highlight is the one region of a photograph that tells a white balancer what the light was, and why removing highlights removes the evidence.

The highlight is the lamp

Light reflected at the surface of a glossy material never entered it, so it never met a pigment. Fresnel's reflectance varies by 5.5% across the visible band and the paint underneath varies by a factor of twenty — which makes a highlight the one region of a photograph that reports what the light was rather than what the object is.

scene · Scene One film, five viewing angles. The same 340 nm film seen from 5 directions. Nothing about the object has changed — not the light, not the material, not the thickness — and the colour swings by ΔE00 = 42. A pigment's spectrum contains no path length and no angle, so it cannot do this; a film's contains both. This is the clean separation between structural and pigmentary colour, and it is geometric rather than chemical.

A colour that moves with the viewer

A thin film has no pigment in it. Its reflectance spectrum is an interference condition containing a path length and an angle, so tilting the sample moves every maximum to a shorter wavelength and changes the colour by 40 units of ΔE. A pigment's spectrum contains neither, and cannot do this at all — which is the cleanest separation between the two kinds of colour there is, and it is geometric rather than chemical.

scene · Scene How much light comes back at each distance from where it went in. The diffuse reflectance kernel of 3 materials at 550 nanometres, computed from the dipole approximation to the diffusion equation. Both axes are logarithmic. The horizontal axis is the distance from the point the light entered, in millimetres; the vertical is how much comes back out per unit area there. Each curve's own diffusion length is marked with a tick. Coated paper returns almost everything within a fifth of a millimetre; marble is still returning light at ten. The reflectance the model wants is the whole of each curve, integrated over the plane, and what an instrument reads is only the part inside its aperture.

A surface has a kernel

Light that enters a translucent material does not come back where it went in. It scatters some thousands of times and leaves a few millimetres away, so what the surface has is not a reflectance but a function of distance — and the reflectance the model wants is that function's integral over the whole plane, which no instrument ever collects.

scene · Scene What the interface does to a reflectance, and the straight line it is taken for. The Saunderson relation between the reflectance inside a pigment layer and the reflectance an instrument reads off it, for a boundary of refractive index 1.50. The curve is the real map; the dashed line joins its two endpoints, which is the straight relation an additive pedestal assumes. They are 0.216 of a reflectance unit apart at their widest, which is 5 times the pedestal itself. The curvature comes from the k₂ term — light reflected back down into the layer from underneath the boundary — which is 0.60 where the outward reflection is 0.04.

A mixture in the variable nobody named

Kubelka–Munk works because absorption and scattering add over a mixture and reflectance does not. What adds is the absorption of the pigment layer, and what an instrument reports is that layer seen through an interface — related by a Möbius function rather than by a constant. Mixing in the reported variable instead of the internal one costs between three and eight ΔE₀₀, and no source this collection quotes says which variable its curves are in.

scene · Scene

Named alongside it

The objects these essays reach for when they reach for this one.

ReflectanceChromaticityFresnelKubelka munkSpecularStandard observerAbsorptionColour constancyColour managementConventionDeclared inputΔE

All concepts