Colour Science & Perception
what the eye settles, and what it cannot
Concept

Absorption — where it appears

Light taken up by a material and turned into something other than light, which is what makes a pigment a pigment. What is absorbed at each wavelength decides a surface's reflectance, and the same molecule that absorbs may re-emit at a longer wavelength.

Named by 10 essays across 6 fields — each of them below, with the objects they name alongside it.

Mixing two paints and stacking two filters are different operations. The same two reflectances combined two ways. Stacking them as filters multiplies the transmittances, which is right for gels in front of a lamp and wrong for pigment stirred into pigment: a stirred mixture is one scattering layer, not two in series, and light meets whichever particle is nearest rather than passing through both. Kubelka–Munk handles it by moving to K/S = (1 − R)²/2R, in which absorption and scattering add by concentration, and inverting afterwards. The two answers differ by ΔE00 = 15.0, and the filter model is the darker of the two because it charges every photon for both pigments.

Paint is not a filter

Stacking two filters multiplies their transmittances. Stirring two pigments together does not multiply their reflectances, because a mixture is one scattering layer rather than two in series — light meets whichever particle is nearest. Treating the two as the same operation is a 15-unit error, and which way it errs turns out to depend on whether the comparison holds the amount of pigment fixed.

scene · Scene The same medium at six path lengths. Beer's law at 6 depths of one absorbing medium. The absorption coefficient is a single spectrum and the only thing changing is how far the light travelled, yet the patches differ in hue by 7.8° as well as in lightness — because absorption is exponential in depth and the observer is linear, so the bands that survive at d = 8 are not a scaled copy of the ones that survive at d = 0.25. Path length belongs to the geometry, not to the substance, which is why this sits in a field about scenes.

The colour is in the thickness

Transmittance is exponential in path length and the observer is linear, so doubling the depth of an absorbing medium squares the transmittance rather than halving the colour. A translucent object therefore has no one colour — its thin edge and its thick middle are different spectra of the same substance, and the hue moves between them.

scene · Scene The blue channel, as the three things multiplied to make it. Silicon's quantum efficiency, the colour-filter dye's transmittance, and their product. The dye is the only stage carrying any colour information and it is clear above about 800 nm — transmittance 0.92 at 900 nm against 0.06 at 550.

Silicon sees past the visible

A sensor's response ends at 1107 nanometres because that is the band gap, and the colour-filter dyes have stopped absorbing three hundred nanometres before it. So all three channels measure the same thing over the last third of the range, and every published sensitivity plot is drawn after the component that hides it.

imaging · Capture One reflectance, four different infrared tails, and what the camera makes of each. The same visible reflectance continued past 780 nm to four different near-infrared values. A spectrophotometer reports only the left-hand part; an unfiltered sensor integrates all of it. The channel spread falls from 0.14 at a tail of 0.05 to 0.02 at 0.85, with nothing about the visible half changed.

Most things are pale in the infrared

A spectrophotometer stops at 780 nanometres and a black cotton shirt reflecting five per cent of visible light reflects more than half the near infrared. The measurement everybody has and the quantity a camera integrates are different quantities, and nothing in the first says so.

imaging · Capture The L cone's sensitivity at three axial pigment densities. Each curve is normalised to its own peak, so the only difference visible is shape. Raising the density from 0.1 to 0.9 widens the curve from 113.6 to 145.9 nm at half height while the peak stays within 5 nm of where it was. That is Beer–Lambert saturating: at the peak the pigment already absorbs nearly everything, so more of it can only catch more light in the wings.

A cone absorbs its own light

A photopigment's absorbance is a property of a molecule; a cone's sensitivity is that molecule stacked in a column deep enough to absorb most of what arrives. The stacking broadens the curve by thirty-five nanometres, and two observers differing in nothing else disagree about a match that is exact for one of them.

eye · Cones The colour of a beam, against the angle it leaves at. A conformal converter — an even layer laid straight onto the die — makes light leaving at θ cross 1/cos θ times as much of it, so it is more completely converted and the beam is warmer at its edge. From the axis to 75° the correlated colour temperature falls by 556 K and the whole difference is ΔE00 16.4. The flat line is the same emitters under a dome, whose path length is the same in every direction by construction: no angular colour at all, exactly, which is what a remote converter is sold for.

A lamp has a direction

A white LED is a blue die under a converter, and light leaving at an angle has travelled further through the converter than light leaving straight up. So the mixture is different in every direction, the beam is bluer in the middle than at its edge, and the number on the box is one direction's worth of a device that has no single colour.

light · Light How much light comes back at each distance from where it went in. The diffuse reflectance kernel of 3 materials at 550 nanometres, computed from the dipole approximation to the diffusion equation. Both axes are logarithmic. The horizontal axis is the distance from the point the light entered, in millimetres; the vertical is how much comes back out per unit area there. Each curve's own diffusion length is marked with a tick. Coated paper returns almost everything within a fifth of a millimetre; marble is still returning light at ten. The reflectance the model wants is the whole of each curve, integrated over the plane, and what an instrument reads is only the part inside its aperture.

A surface has a kernel

Light that enters a translucent material does not come back where it went in. It scatters some thousands of times and leaves a few millimetres away, so what the surface has is not a reflectance but a function of distance — and the reflectance the model wants is that function's integral over the whole plane, which no instrument ever collects.

scene · Scene A 40-nanometre limit written in nanometres and written in energy. The transition width a reflectance is allowed, across the spectrum, for two ways of stating the same sharpness. Written in nanometres it is 40 everywhere. Written as a fixed spread of photon energy, which is how an absorption band's width is set, it is 40 at 550 nanometres and grows as the square of the wavelength: 21 at 400 and 67 at 700. The steps are the quantisation the calculation actually imposes.

A limit written in energy charges the reds

A slope limit on reflectance is usually written in nanometres and applied the same way across the spectrum. An absorption band's width is closer to a fixed spread of photon energy, which is nearly twice as many nanometres at 700 as at 500. Written that way, a limit that is forty nanometres at 550 is kinder to the object-colour solid overall — 489 of 913 directions lose a per cent rather than 544 — and it charges the reds more. Which directions pay is decided by one thing: whether their optimal edges fall above or below the reference wavelength.

limits · Limits Which way a tint turns a pigment's hue, made in paint and made in light. For eight pigments tinted nineteen parts white to one of colour, the Oklab hue turn from the pure pigment: of the tint made in paint (upper bar) and of the additive mixture with white at the same luminance (lower bar). For seven of the eight the two point in opposite directions. The orange turns +13.5° in paint and −13.9° in light.

A tint in paint turns the other way

A pale colour can be made two ways: by stirring white pigment into a coloured one, or by adding white light to it — which is what a halftone on white paper and a display both do. At the same luminance the two tints are not the same colour. For seven of eight pigments they turn the hue in opposite directions, an orange by +13.5 degrees in paint and −13.9 in light, and the paint tint is the more colourful of the two every time. The cause is in the reflectance: diluting a pigment moves its absorption edge, and adding light does not.

brain · Appearance How steep an edge a band draws, and what it costs. A Gaussian absorption band of stated width produces a reflectance edge whose own width depends on how deep the band is, because the exponential saturates: where the absorbance is large the reflectance is already nought and the edge is over. A forty-nanometre band at an absorbance of 3 draws an edge 32 nanometres wide; at 12 it draws one 21 nanometres wide. Below an absorbance of 2.3 the band never reaches a reflectance of a tenth at all and has no edge in this sense. The dashed lines are each band's own width, which is the number a slope limit would have been given.

A sharp edge is bought with depth

A slope limit on reflectance was introduced as the weakest honest statement of a pigment's bluntness, with a band-shape limit named as the stronger version to be written later. Written, it is not stronger. Three absorption bands none narrower than forty nanometres reach further than a forty-nanometre slope limit in 94 of 154 directions of the object-colour solid, because a band's width and the width of the reflectance edge it draws are different quantities — and what converts one into the other is how much colorant is in the film.

limits · Limits

Named alongside it

The objects these essays reach for when they reach for this one.

ReflectancePigmentKubelka munkScatteringStandard observerSubtractive mixtureBeer lambertBoundCamera rawChromaticityΔEIlluminant

All concepts