Colour Science & Perception
what the eye settles, and what it cannot
Concept

Optimal colours — where it appears

Reflectances taking only the values zero and one with at most two transitions, which are the extreme points of the object-colour solid. Every real surface lies inside the region they enclose, which is what makes the bound they trace a theorem rather than a survey.

Named by 10 essays across 4 fields — each of them below, with the objects they name alongside it.

What no surface can be more colourful than. The MacAdam limits at 4 lightnesses under D65, each computed by sweeping two-transition reflectances over the whole band and keeping those that land at the target luminance factor. This is a physical bound rather than a gamut: a reflectance above 1 is a surface that emits, so no pigment anybody invents will ever put an object colour outside these curves. The boundary shrinks steeply as the surface lightens, from 0.310 at Y = 0.1 to 0.028 at Y = 0.9 — a very light surface has almost no room to be colourful, and that is physics rather than pigment chemistry. Drawn against it is sRGB at the same luminance factor rather than as a primary triangle, because a triangle is what a display can reach at some luminance and the bound is what a surface can reach at one; matched properly, sRGB covers 36% at Y = 0.1, 40% at Y = 0.3, 40% at Y = 0.6, 21% at Y = 0.9. The faint triangle is the familiar figure, kept only to show how much it misleads.

No surface can be that colourful

There is a hard bound on object colour that no pigment will ever move, and it follows from a reflectance being at most 1. Its boundary is generated by two numbers, it shrinks by a factor of eleven from dark to light — and measured against it properly, sRGB reaches 40% of what a surface could be at mid lightness while Rec. 2020 reaches 106%.

scene · Scene Outside the set of colours a reflecting surface can be. How far each stock sits from the boundary of the object-colour solid, as a fraction of the bound. The line at zero is the boundary: a perfect diffuser sits exactly on it, and every reflectance ever made sits to its left. The pale marker is the sheet measured with the ultraviolet excluded and the dark one with it included. Two of the six cross the line — they are brighter, in a direction that can be written down, than any reflecting surface of their colour could be. This is a proof rather than a hull: for each sample a direction is found in which the largest value any reflectance can reach is computed exactly, and the sample exceeds it.

A white that is not a reflectance

The object-colour solid is the hardest boundary in colorimetry — the set of tristimulus values any reflecting surface can produce, with no assumption about pigments in it at all. A coated press stock under a measurement standard's own lamp sits 1.5 per cent outside it, and a heavily brightened one 4.0, and with the ultraviolet removed both come back inside.

limits · Gamut What share of the diagram the sRGB triangle covers, in twelve published coordinate systems. Each row is a chromaticity diagram somebody has printed, and each bar is the fraction of the enclosed visible area that the sRGB triangle covers in it. Every row describes exactly the same observer and exactly the same gamut. The answer runs from 8.5% to 38.4%, a factor of 4.52, because area is not preserved by the projective maps that carry one of these diagrams to another. The familiar "about a third" is a fact about CIE xy.

Two thirds is not a property of the eye

It has been said from the beginning here that about two thirds of the chromaticity diagram cannot be shown on a screen. The figure is right, on the diagram it was measured on, and across twelve published diagrams the same triangle covers anything from 8.5 to 38.4 per cent of the same locus. Counting stimuli instead gives an answer that does not move.

matching · Gamut Which appearances a surface can have, lightness by lightness. The same lattice of lightness, chroma and hue a specification is written in, 10488 points, inverted under daylight with the observer adapted to it. Each row is one lightness, split into three shares: appearances a reflecting surface can have, appearances that are a light but that no surface can return, and appearances with no light under them at all. Over the whole lattice the first is 66 per cent, the second 23 and the third 11. At J 90 a surface can have 38 per cent of the row.

A third of the appearance box is no surface

An appearance specification is written as a lightness, a chroma and a hue, and the model's inverse turns any such triple into three numbers. A tenth of the space turns into something that is not a light at all. A further quarter turns into a light no reflecting surface can return, because a surface cannot give back more than all the light at any wavelength. So a third of the space a paint, a print or a dye is specified in cannot be made from paint, print or dye, and at lightness 90 nearly two thirds cannot.

brain · Appearance What a slope limit costs the object-colour solid, direction by direction. For each transition width, how much of its ideal reach the solid keeps: the median direction, the tenth percentile, and the worst. At twenty nanometres the median keeps 0.997 and the tenth percentile 0.985; at eighty they keep 0.946 and 0.766, and at 160 0.826 and 0.417. The worst direction falls from 1.00 at five nanometres to 0.20 at 160, with directions reaching under five units beyond black set aside. The cost is in a corner only at widths sharper than an ordinary pigment's.

The limits assume a pigment that switches instantly

The hardest boundary in colorimetry is reached by reflectances that jump between nought and one at a wavelength, and no material does that. Constrain the jump to take twenty nanometres — a sharp dye — and the median direction of the object-colour solid loses under half a per cent of its reach. Constrain it to eighty, an ordinary pigment, and the median loses five per cent, the tenth percentile nearly a quarter, and seven directions in ten lose more than one. The cost is in a corner only for chemistry sharper than paint.

limits · Limits How many directions a slope limit costs, under four lamps. For each transition width and each lamp, the share of the solid's directions that lose more than one per cent of their reach — each lamp's solid against its own ideal. Daylight, a tungsten lamp and a phosphor LED run close together. The three-emitter LED, whose power sits in lines at 455, 530, 625 nanometres, costs 62 directions at forty nanometres where daylight costs 183, and by eighty — about the spacing of its lines — it costs 214 against 218.

Three lines spare a slow pigment

A pigment that cannot switch faster than forty nanometres loses more than a per cent of its reach in 183 of the object-colour solid's 305 directions under daylight. Under an LED whose light sits in three narrow lines, it loses that much in 62. Between the lines almost nothing is measured, so a slow reflectance can do its changing there — until its transitions are as wide as the lines are far apart, at which point the lamp stops helping and the count jumps to daylight's.

limits · Limits A 40-nanometre limit written in nanometres and written in energy. The transition width a reflectance is allowed, across the spectrum, for two ways of stating the same sharpness. Written in nanometres it is 40 everywhere. Written as a fixed spread of photon energy, which is how an absorption band's width is set, it is 40 at 550 nanometres and grows as the square of the wavelength: 21 at 400 and 67 at 700. The steps are the quantisation the calculation actually imposes.

A limit written in energy charges the reds

A slope limit on reflectance is usually written in nanometres and applied the same way across the spectrum. An absorption band's width is closer to a fixed spread of photon energy, which is nearly twice as many nanometres at 700 as at 500. Written that way, a limit that is forty nanometres at 550 is kinder to the object-colour solid overall — 489 of 913 directions lose a per cent rather than 544 — and it charges the reds more. Which directions pay is decided by one thing: whether their optimal edges fall above or below the reference wavelength.

limits · Limits What a fourth emitter costs, by where it is put. A three-emitter LED with one more emitter added at each position from 470 to 610 nanometres, and for each lamp the number of the object-colour solid's directions that lose more than a per cent of their reach to a 40-nanometre transition limit. The three-emitter lamp itself costs 62 of 312. A fourth emitter in the middle of the blue-to-green gap, at 490 nanometres, costs 172; one at 540, beside the green emitter, costs 65. The two dips sit on the existing lines and the two peaks sit between them.

A fourth emitter spends the gap it fills

A three-emitter LED lets a pigment that takes forty nanometres to switch reach most of its ideal solid, because the lamp is dark where the pigment is slow. Adding a fourth emitter to render better takes that darkness back — but only if it is put in the middle of a gap. At 490 nanometres it costs 172 of the solid's 312 directions against the three-emitter lamp's 62, and renders two points worse. At 540 it costs three directions and renders two and a half points better.

limits · Limits The rescue is spent on light between the lines, not on width. The three emitters of a narrow-band LED broadened together, from their nominal widths up to six times them, plotted against the light left in the darkest of the lamp's two gaps as a share of its peak. Up is the share of the object-colour solid's directions that lose more than a per cent of their reach, at three transition limits, with each limit's cost under daylight marked at the right. At forty nanometres half of the rescue is gone by a floor of 7.4 per cent — emitters only 1.30 times their nominal width — and all of it by about a fifth. At twenty nanometres and at eighty there is little to lose either way.

The gap has to be dark, not the line narrow

A lamp whose light sits in three narrow emitters lets a blunt pigment reach most of its ideal solid, and the reason was given as the spacing of the lines. Broadening those emitters without moving them says otherwise. At 1.3 times their nominal width the lamp still looks like a line spectrum, its closest spacing has not changed at all, and half the rescue is gone — because the darkest point of the narrow gap has risen from one per cent of the lamp's peak to seven.

limits · Limits How steep an edge a band draws, and what it costs. A Gaussian absorption band of stated width produces a reflectance edge whose own width depends on how deep the band is, because the exponential saturates: where the absorbance is large the reflectance is already nought and the edge is over. A forty-nanometre band at an absorbance of 3 draws an edge 32 nanometres wide; at 12 it draws one 21 nanometres wide. Below an absorbance of 2.3 the band never reaches a reflectance of a tenth at all and has no edge in this sense. The dashed lines are each band's own width, which is the number a slope limit would have been given.

A sharp edge is bought with depth

A slope limit on reflectance was introduced as the weakest honest statement of a pigment's bluntness, with a band-shape limit named as the stronger version to be written later. Written, it is not stronger. Three absorption bands none narrower than forty nanometres reach further than a forty-nanometre slope limit in 94 of 154 directions of the object-colour solid, because a band's width and the width of the reflectance edge it draws are different quantities — and what converts one into the other is how much colorant is in the film.

limits · Limits

Named alongside it

The objects these essays reach for when they reach for this one.

Object-colour solidMacadam limitsBoundPigmentReflectanceGamutSpectral power distributionWavelength gridDisplay gamutIlluminantNarrow band displaysWhite LED

All concepts