Colour Science & Perception
what the eye settles, and what it cannot
Concept

Optical brighteners — where it appears

Dyes that absorb ultraviolet and re-emit it as blue, making a sheet return more light in a band than reached it there. The trick works because the absorption sits where the eye is blind and the emission where it is not, so the sheet gains blue and loses nothing visible.

Named by 30 essays across 8 fields — each of them below, with the objects they name alongside it.

A sample with two reflectance curves, and neither below one. The apparent reflectance of an optically brightened sample, measured under D65 and A. It exceeds 1 — the shaded band — which no reflector can do: more light leaves at these wavelengths than arrives at them, because the sample absorbs in the violet and re-emits in the blue. And the two curves differ, so the sample has no single reflectance to store. The effect drawn here is a floor: most of the excitation band lies below 380 nm, outside the range computed here.

Some paper is brighter than white

The reflectance model assumes light leaving at a wavelength arrived at that wavelength. A fluorescent sample breaks the assumption, has no reflectance curve at all, and is in almost every sheet of white paper sold.

light · Light A sample with two reflectance curves, and neither below one. The apparent reflectance of an optically brightened sample, measured under D65 and A. It exceeds 1 — the shaded band — which no reflector can do: more light leaves at these wavelengths than arrives at them, because the sample absorbs in the violet and re-emits in the blue. And the two curves differ, so the sample has no single reflectance to store. The effect drawn here is a floor: most of the excitation band lies below 380 nm, outside the range computed here.

A surface that is not a multiplication

Every argument here about what light does to a surface begins by multiplying two spectra together. A surface with a brightener in it takes light at one wavelength and returns it at another, so it is a full operator rather than a diagonal one — and it does not have a reflectance at all.

scene · Scene Six functions of wavelength, and the six different places they stop. Every table this collection integrates against, drawn over the range the body that published it defined it on. The scale is logarithmic so that the ultraviolet and the near infrared both fit. The bottom row is the range used here before the infrared band was added, and it is the intersection of the two rows that matter for an eye looking at a reflector — which is the right answer only while everything in the integral is being multiplied together. The daylight basis runs 80 nanometres further down than that intersection, and it was published that way because the ultraviolet in daylight is what makes a brightened sheet of paper glow. The analytic row is drawn to the edge of the plot because it has no edge: Planck's law is a formula and is exact at every wavelength, which is why illuminant A needs no table at all.

The tables do not stop together

This collection integrates from 380 to 780 nanometres, and decided once, in writing, that the range could not honestly be widened. The argument was correct at the long end and wrong at the short one — the CIE publishes the daylight basis from 300 nanometres, and publishes it from there for exactly the reason it matters.

light · Light A fluorescent sample is a matrix, and a reflectance is only its diagonal. The Donaldson matrix of a brightened sheet: how much light leaves at each wavelength for light arriving at each wavelength. A reflecting surface has entries on the diagonal and nowhere else, which is exactly the statement that light leaving at 440 nanometres arrived at 440. The block off the diagonal is the fluorophore — it takes light between about 305 and 420 nanometres and returns it between 400 and 500, wherever in that band it was absorbed, which is why the block is a rectangle rather than a smear along the diagonal. A spectrophotometer that reports a reflectance is reporting the diagonal and folding the block into it at whatever weight its own lamp happened to give.

A reflectance is a diagonal

A reflecting surface returns light at the wavelength it arrived at, so its whole description is one number per wavelength. A fluorescent one returns it somewhere else, so its description is a square matrix — and the curve every instrument reports is that matrix's diagonal with the rest of it folded in at whatever weight the lamp happened to give.

light · Light A radiance factor, split into the part that was reflected and the part that was not. The two components of what leaves a heavily brightened sheet under M₁ — D50 including its ultraviolet. The lower band is the reflected component, which is what a reflectance curve means and is everything a reflectance-based model can hold. The band above it is light emitted at wavelengths it did not arrive at, and its total is decided by how much ultraviolet the source had rather than by anything about the sheet's colour. The line at one is the boundary a reflecting surface cannot cross; the sum reaches 1.21 at 430 nanometres.

The eye weights where the light is not

A brightened sheet returns a quarter more light than arrives at 430 nanometres, and it is three tenths of one per cent brighter for it. The luminous efficiency function is 0.017 there against 1.0 in the middle of the band, so the whole effect lands in the blue-yellow axis — brighter than white is a colour claim wearing a brightness word.

matching · Cones Two sheets with the same reflectance and two different colours. A brightened sheet and a dyed one built to match it under an instrument with no ultraviolet. Under that instrument the pair agrees to ΔE00 0.00, which is a rounding and is true by construction — the dyed sheet's reflectance is the curve the brightened one measured. Under an instrument that includes the ultraviolet they are 7.1 apart, and under daylight 10.6. This is not ordinary metamerism: the two sheets do not differ in reflectance anywhere the eye can see, so no change of light puts them back together and no adaptation removes the difference. One of them is a curve and the other is an operator.

Two sheets that match until the window

Ordinary metamerism is two reflectances that agree under one light and not another, and it can always be undone by putting the first light back. A dyed sheet and a brightened one have the same reflectance everywhere an eye can see, agree exactly under any lamp with no ultraviolet, and separate by ten units under daylight — and no change of light puts them back together.

scene · Scene What a sheet of glass takes out of the band a brightener eats. The transmittance of four glazings across the short-wave band, with the brightener's own absorption shaded underneath. The overlap between a curve and the shading is what the sheet behind that glass has to work with. Ordinary window glass stops below about 310 nanometres and leaves most of the band; laminated glass has a plastic interlayer that was put there to hold the sheet together in a crash and happens to absorb almost to 380; a filter sold to protect a print removes the band entirely. The curves are logistic edges at stated wavelengths rather than measurements of particular products.

The window is part of the light

A viewing condition here has always been a spectrum and a geometry. For anything fluorescent it needs a third thing — the transmittance of whatever the daylight came through — because ordinary window glass, a laminated windscreen and a museum filter remove three quite different parts of the band a brightener eats, and the sheet is a different colour behind each.

scene · Scene Six sheets, four standard measurement conditions, and every pair of them. How far apart two measurement conditions put the same sample. Darker is further. The top row has no brightener in it and every pair agrees to within a unit except the ones involving M₃, whose difference is cross-polarisation removing the interface reflection and is a change of geometry rather than of spectrum. Every row below it disagrees, and the M₁ against M₂ column reaches ΔE00 7.7 — several times any tolerance a printer would accept, on one sheet measured twice by two instruments that are both working correctly. The numbers under the columns are the means.

An instrument brings its own light

ISO 13655 names four measurement conditions and they are usually read as four degrees of care. They are not. They are four different quantities — on an unbrightened sheet all four agree to a rounding, and on a brightened one they are up to seven and a half units apart, with every instrument in calibration and every answer correct.

applied · Delivery What a proof on an unbrightened sheet cannot reach. The paper white of a heavily brightened stock beside the paper white of an unbrightened one, both under an ultraviolet-included instrument. They are ΔE00 9.8 apart and 10.3 of that is in the blue-yellow axis. A proofing system on the unbrightened sheet can print towards the brightened one only by adding ink, which makes the paper darker rather than bluer; it cannot add light at 435 nanometres because it has no brightener and its own lamp is the one in the room. This is why a soft proof and a hard proof of the same job disagree about the white, and why the disagreement is in one direction.

A proof cannot glow

A proof is a different sheet of paper pretending to be the production one, and the pretence works by adding ink until the two agree. It cannot work for a brightened stock, because the direction the proof has to travel is towards more blue at the same lightness and every ink a proofer owns moves it towards less light instead.

applied · Delivery How much of a whiteness figure is the sheet, and how much is the lamp. Each bar is how many points of CIE whiteness a stock has above an unbrightened sheet of the same base, measured with an ultraviolet-included instrument. The dark part is what survives when the ultraviolet is removed — the part that is a property of the paper. On average 82 per cent of the scale is the pale part, which is a property of the instrument's lamp. A whiteness figure without a measurement condition beside it is therefore not a measurement of a sheet; it is a measurement of a sheet and a lamp, quoted as though it were the first.

Whiteness is mostly the lamp

The CIE whiteness formula ranks white samples the way people do, which is what it was built for and is not in question. What is in question is what it is a measurement of — take the ultraviolet out of the instrument and 82 per cent of the scale collapses, because the part that separates a premium sheet from an ordinary one was contributed by the lamp.

difference · Metric Two lamps of the same colour, and one sheet that is two colours under them. The same brightened sheet under a xenon flash, the same flash behind its cover glass, and a phosphor-converted white LED of nearly the same chromaticity. Each patch is computed relative to its own lamp's white, which is what a perfect white balance does — so everything a camera can see and correct has already been removed. What is left is ΔE00 11.8 between the first and the last, against 3.2 between the two lamps themselves. The LED has no emission below 380 nanometres at all, because its pump die is at 450, so the sheet simply does not fluoresce under it and nothing in the photograph records why.

A camera cannot record the excitation

Two lamps of nearly the same chromaticity, one with ultraviolet and one with none, put a brightened sheet twelve units apart after a perfect white balance. Nothing in the camera measured the difference — the filter stack removed the band before the sensor saw it — so the correction that would fix the picture needs a quantity the file does not contain.

imaging · Capture The lamps the four conditions shine, where they differ. The short-wave half of what each measurement condition puts on the sample, plotted to 560 nanometres because past that the three are indistinguishable in shape. M₁ is D50 with its ultraviolet; M₂ is the same lamp behind a cut filter at 400 nanometres, and at 360 it is 0.0 per cent of what M₁ delivers; M₀ is a tungsten lamp, which has some ultraviolet, has less than daylight, and is not specified at all by the standard — so two M₀ instruments need not agree with each other. M₃ is not plotted because its lamp is M₂'s; what makes it a fourth condition is a polariser.

The lamp that stopped emitting ultraviolet

A blue-pumped white LED has a die at 450 nanometres and emits nothing shorter. Between about 2005 and 2020 that lamp replaced almost every other indoor source, which removed the excitation supply from a great many rooms — so brightened materials stopped glowing indoors without a single one of them being reformulated.

imaging · Capture Outside the set of colours a reflecting surface can be. How far each stock sits from the boundary of the object-colour solid, as a fraction of the bound. The line at zero is the boundary: a perfect diffuser sits exactly on it, and every reflectance ever made sits to its left. The pale marker is the sheet measured with the ultraviolet excluded and the dark one with it included. Two of the six cross the line — they are brighter, in a direction that can be written down, than any reflecting surface of their colour could be. This is a proof rather than a hull: for each sample a direction is found in which the largest value any reflectance can reach is computed exactly, and the sample exceeds it.

A white that is not a reflectance

The object-colour solid is the hardest boundary in colorimetry — the set of tristimulus values any reflecting surface can produce, with no assumption about pigments in it at all. A coated press stock under a measurement standard's own lamp sits 1.5 per cent outside it, and a heavily brightened one 4.0, and with the ultraviolet removed both come back inside.

limits · Gamut A whiteness measurement has a date on it. A brightener is consumed by the ultraviolet that makes it glow: the molecule that absorbs a photon occasionally does something other than re-emit it, and what it does is break. So the loading falls with accumulated dose and the sheet's whiteness falls with it, from W 123 to 88 — most of the way back to the unbrightened base. The fall is steepest at the start because the absorption saturates, so the first molecules lost are the ones that were doing the least work and the curve is convex from the beginning. The dose axis is in arbitrary units whose half-life is stated; what is not arbitrary is the shape.

The brightener is being used up

The molecule that absorbs an ultraviolet photon occasionally does something other than re-emit it, and what it does is break. So a sheet's whiteness has a half-life, the fall is steepest at the start, and a specification quoting a whiteness figure without a date is quoting a property of a sheet that no longer exists.

limits · Limits How blue the sheet reads, and how much of that is the room. Chroma in an appearance model, with the observer adapted to the light the sheet is under. The three markers on each row are an average, a dim and a dark surround; the open marker at the left is the same sheet with the ultraviolet removed. Every stock is close to neutral without the excitation and carries real chroma with it, at a hue of about 295 degrees — blue-violet — so the colour is the fluorescence and not the substrate. And it falls by nearly half between a bright room and a dark one, which makes how blue a sheet looks a property of where it is being looked at.

A brighter white still looks white

Colorimetry says a brightened sheet is nine units of b* from neutral, which sounds like a visible blue. An appearance model with the observer adapted to the room says it carries eleven units of chroma at a hue of 295 degrees — genuinely blue-violet — and that the number falls by nearly half between a bright room and a dark one. What it cannot say is why anybody calls the result white.

brain · Appearance A radiance factor, split into the part that was reflected and the part that was not. The two components of what leaves a coated press stock under M₁ — D50 including its ultraviolet. The lower band is the reflected component, which is what a reflectance curve means and is everything a reflectance-based model can hold. The band above it is light emitted at wavelengths it did not arrive at, and its total is decided by how much ultraviolet the source had rather than by anything about the sheet's colour. The line at one is the boundary a reflecting surface cannot cross; the sum reaches 1.15 at 430 nanometres.

The ultraviolet is half the product

A fluorescent sample's departure from the reflectance model is exactly proportional to the ultraviolet the lamp carries — to twelve figures, over a range that includes zero. It is the only one of the round's four departures that really is a product of two magnitudes, and the reason is a rule about how molecules relax rather than anything about arithmetic.

light · Light Six functions of wavelength, and the six different places they stop. Every table this collection integrates against, drawn over the range the body that published it defined it on. The scale is logarithmic so that the ultraviolet and the near infrared both fit. The bottom row is the range used here before the infrared band was added, and it is the intersection of the two rows that matter for an eye looking at a reflector — which is the right answer only while everything in the integral is being multiplied together. The daylight basis runs 80 nanometres further down than that intersection, and it was published that way because the ultraviolet in daylight is what makes a brightened sheet of paper glow. The analytic row is drawn to the edge of the plot because it has no edge: Planck's law is a formula and is exact at every wavelength, which is why illuminant A needs no table at all.

The grid is a range, not an index

Three of the four departures in this round restore an argument the model dropped. The fourth does not — the 380-to-780-nanometre grid is the range of the one argument the model kept, chosen in the first weeks and never revisited. It costs 6.70 ΔE₀₀ on a coated printing paper, it is the cheapest of the four to fix, and it is the one still unfixed.

light · Light What adaptation cannot remove from an orange tint, with and without a thin dot edge. For a reader fully adapted to brightened office paper, the orange tint's hue turn against its solid beyond what a non-fluorescent sheet of the same colour leaves, at coverages from five to sixty per cent, with a uniform ink film and with rims of three, six and twelve micrometres. The residue is largest at the palest tint for every rim, and every wider rim raises it: at a fifth coverage from 6.8° to 7.9°.

A thin dot edge lets the glow back in

A pale tint printed on brightened paper keeps part of its hue turn however fully a reader adapts to the sheet — ten degrees for a fifth-coverage orange where a non-fluorescent sheet of the same colour leaves three — because the ink's vehicle puts out the brightener's glow under the solid and the tint's bare paper keeps it. That census gave every dot a uniform film. A real dot thins at its edge, a thin film lets ultraviolet through, and at the pale end of a ramp most of a dot is edge. The prediction was that the edge would restore the glow under the tint's dots, shrink the residue by a third at a fifth coverage and move the worst of it to the mid-tones. The edge does restore the glow — nine times as much under a small dot with a twelve-micrometre rim. And the residue grows: 6.8 degrees to 7.9 at a fifth coverage, 7.2 to 9.0 at a twentieth. The residue is the tint glowing where the solid does not, and more glow under the tint's dots is more of the difference. The palest tint keeps the most, with or without an edge.

brain · Appearance What adaptation cannot remove from an orange ramp, screen by screen. For an orange ramp on brightened office paper, the hue turn against the solid that a reader fully adapted to the sheet still sees beyond what the sheet's colour accounts for, on conventional screens of 100, 150, 200 and 300 lines and on stochastic screens of 10, 20 and 35 µm dots, every dot with a six-micrometre rim. The 150-line screen falls from 8.1° to 5.7° along the ramp; the 20 µm stochastic screen stays near 9.0°; the 10 µm one rises, from 10.4° to 11.4°. The axis starts at 4.5°.

Stochastic dots hold the glow at every tint

On brightened paper a halftone tint keeps a hue turn that a reader fully adapted to the sheet cannot remove, because the paper's glow survives under the ink where the solid puts it out, and a dot's thin edge lets more of it back. A dot's size at a given coverage is set by the screen. Across conventional rulings from 100 to 300 lines the residue rises at every coverage for every pigment, a finer screen making every dot more edge. A stochastic screen of twenty-micrometre dots holds it flat — the orange within a quarter of a degree from five per cent to sixty, starting where a 300-line screen starts — as predicted. What the prediction did not say is where the switch costs: not the pale tints, by under a degree, but the mid-tones, by three or four, because a conventional screen's mid-tone dots are large and mostly full film. On ten-micrometre dots, all edge, the ramp turns over and the mid-tone keeps more than the pale tint. At any one coverage the residue is set by the dot's diameter alone, whichever screen printed it.

brain · Appearance What merging the spots gives back along an orange ramp. For an orange ramp on brightened office paper, the turn a reader fully adapted to the sheet still sees beyond the sheet's colour, on a stochastic screen of twenty-micrometre square spots kept separate and merged where they touch, beside the round-dot stochastic screen and a 150-line screen. Merged and separate agree until the spots begin to touch near thirty per cent; at sixty per cent the merged screen keeps 6.9° against the separate spots' 8.6°. The axis starts at 4.5°.

Merged spots give the mid-tones half the glow back

On brightened paper a halftone tint keeps a hue turn a reader adapted to the sheet cannot remove, and a stochastic screen's small dots, being mostly thin edge, keep it high along the whole ramp — three times the 150-line screen's cost in the mid-tones. That census kept every dot separate. A real stochastic screen's spots touch and merge, and a shared edge between two spots is no edge of the ink. The prediction was that a merged screen would follow the separate-dot curve to about thirty per cent and then fall towards the conventional screens, giving back half the mid-tone cost by sixty. It does, almost exactly. Square spots twenty micrometres on a side, switched on in a dispersed order, stay apart up to a fifth coverage and start touching near thirty per cent; by sixty, nine in ten touch, the rim has fallen from 84 per cent of the ink to 50, and the merged screen keeps the orange's residue at 6.9 degrees against the separate spots' 8.6 and the 150-line screen's 5.7 — giving back 58 per cent of the cost. Every pigment gets back the same share, 55 to 58 per cent, because the share is set by the geometry of the ink, not by its colour.

brain · Appearance Clustered spots along an orange ramp. For an orange ramp on brightened office paper, the turn a reader fully adapted to the sheet still sees beyond its colour, on stochastic screens of twenty-micrometre spots switched on singly and in clusters of two, three and four, beside 150- and 300-line screens. At five per cent clusters of four leave 8.14° against the single spots' 8.94° and the 150-line screen's 8.12°; at sixty per cent, 6.00° against 6.90° and 5.67°. The axis starts at 5°.

Squares of four print a pale tint like a 150-line screen

On brightened office paper a stochastic screen's twenty-micrometre spots are mostly rim while they stay apart, and the rim lets the paper's glow through, so the palest tints carry the screen's whole cost in hue a fully adapted reader still sees. Merging gives back half of it in the mid-tones, where the spots touch, and nothing in the pale tints, where they do not. A second-order screen switches its spots on in clusters from the first tint, and the prediction was that clusters of four would take the orange's pale-tint residue down by about a degree, to within half a degree of a 300-line screen, while the sixty-per-cent tints stayed where the merged first-order screen leaves them. Squares of four do better in the pale tints than predicted and differ where predicted to agree. At five per cent they take the orange from 8.94 degrees to 8.14 — 0.02 above a 150-line screen and 0.81 below a 300-line one — and every pigment lands within a tenth of a degree of the 150-line screen. At sixty per cent they keep the orange 0.9 degrees below the first-order screen, where pairs and Ls come back to within a quarter. From ten per cent on, the 150-line screen pulls ahead.

brain · Appearance Growing clumps follow the 150-line screen along the ramp. For an orange ramp on brightened office paper, the turn a reader fully adapted to the sheet still sees beyond its colour, on single stochastic spots merged where they touch, on squares of four, on thirteen clumps grown from those squares as the tint darkens, and on a 150-line screen. The growing clumps start as the squares, 8.14°, and follow the 150-line screen from there: 7.22° against 7.09° at thirty per cent, 5.65° against 5.67° at sixty. The axis starts at 5°.

A growing clump prints like the screen with as many dots

On brightened office paper a halftone's ink lets the paper's glow through at its thin rim, and the share of the ink that is rim decides how much hue a fully adapted reader still sees turned. A stochastic screen of squares of four prints the palest tint like a 150-line screen and falls behind it from ten per cent, because its clusters multiply where a conventional dot grows. A hybrid grows each cluster as the tint darkens, the number of clumps held, and the prediction was that it keeps the squares' pale tint, reaches within a tenth of a degree of the 150-line screen by thirty per cent, and stays slightly above it through the mid-tones. With thirteen clumps on the census's tile it follows the 150-line screen within two tenths of a degree at every coverage, within a twentieth at twenty per cent, and dips just below it at sixty. The reason is a count. Thirteen clumps on a tile 640 micrometres across are as many dots per area as a 143-line screen; twenty-six follow the 200-line screen and fifty-two the 300-line. A clump's irregular place on the tile does not matter to the glow; how many clumps share the ink does.

brain · Appearance Most of the residue is not at the rim. At each coverage of the orange ramp, the residue a single clump on the tile leaves — the least rim the tile can hold — beside thirteen clumps'. The single clump keeps 92 per cent of the thirteen clumps' residue at five per cent and 94 at sixty: the rest of the turn is the tint's bare paper glowing beside ink that does not.

The rim was never most of the glow

On brightened paper a halftone tint keeps a hue turn a reader fully adapted to the sheet cannot remove, and five essays have chased the part of it that lives at the ink's thin rim — merging spots, clustering them, growing them — down to a rule: the clump count sets the residue, and only coarser patterns lower it. The proposal was a screen coarse in the pale tints and finer as the tint darkens, and the prediction that six clumps on the tile beat the 150-line screen by more than half a degree below twenty per cent. They beat it by 0.11 to 0.17. Scheduled six, thirteen and twenty-six clumps save a third of a degree at ten per cent and give back a fifth at sixty. The reason is the floor. One clump on the tile — the coarsest pattern it can hold, nearly all its rim gone — still leaves 7.48 degrees of an orange's 8.14 at five per cent and 5.30 of 5.65 at sixty. What screening can move is the rim's tenth; the other nine tenths is bare paper glowing beside ink that does not.

brain · Appearance A lighter ink swings the residue through nought. For a five-per-cent tint on brightened office paper, printed instead with the same pigment diluted to a share of its strength over more of the paper — matched in colour on a non-fluorescent sheet — the hue turn a reader fully adapted to the sheet still sees, signed, against the dilution. The orange's -7.2° at full strength passes nought near 0.54 and reaches 10.3° at a quarter.

A light ink can cancel the glow at one strength

A pale tint on brightened paper keeps a hue turn a reader fully adapted to the sheet cannot remove, and nine tenths of it survives every screen, because it is the tint's bare paper glowing beside ink that puts the glow out. A light ink — the same pigment diluted, printed over more of the paper — was the proposed lever, and the prediction that a quarter-strength ink lowers a five-per-cent orange's residue by a third. It does not lower it; it reverses it, from −7.2 degrees to +10.2. Somewhere between, the residue passes through nought, and for every one of eight pigments there is a strength that cancels it: 0.41 for the red, 0.54 for the orange, 0.80 for the blue and the cyan at a five-per-cent tint. The cancelling strength moves by under a tenth from five per cent to forty, so one ink per pigment keeps every pale tint within a degree and a quarter to twenty per cent, where full-strength ink leaves up to nine. The lever is real; it has a setting, and the light inks printers carry are diluted past it.

brain · Appearance One ink overshoots on the light sheet and falls short on the premium. Every pigment printed at the strength that cancels its ten-per-cent residue on the office sheet, its coverage matched to each sheet's own five-per-cent target: the residue a reader adapted to each sheet still sees, signed. On the office sheet it is near nought; on the light sheet seven of eight pigments' residues have turned past nought the other way, and on the premium sheet all eight keep the full-strength ink's sign, by under 1.8 degrees.

One light ink serves three papers within two degrees

On brightened office paper a pale tint keeps a hue turn even for a reader fully adapted to the sheet, and each pigment has one light-ink strength — the pigment diluted and printed over more of the paper — at which that residue vanishes. The prediction for a printer with several stocks was that the cancelling strength falls as the brightener loading rises, and that the office sheet's ink leaves a premium sheet's pale tints within two degrees and a lightly brightened sheet's within one. The strength does fall, at every step and for every pigment — by a fifth for the orange and the yellow, by under one per cent for the green. The office ink keeps the premium sheet within 1.8 degrees, as predicted, but the light sheet only within 1.8 too: it overshoots there, turning seven of eight pigments' residues past nought the other way, and falls short on the premium sheet for all eight. Either way it removes more than four fifths of what the full-strength ink leaves.

brain · Appearance The fresh sheet's ink holds until half the brightener is gone. On the premium sheet as its brightener bleaches, the worst residue any of eight pigments leaves from five to twenty per cent: printed at full strength, with the fresh premium sheet's light inks, and with the office sheet's. The fresh premium inks stay under two degrees to half bleached (25%: 1.75°, 50%: 1.80°, 75%: 2.35°); the office inks, 1.80° on the fresh sheet, stay under one and a half once any of the brightener has bleached.

An ink for a fading sheet is set for its middle age

A light ink cancels a pale tint's residual hue turn on brightened paper at a strength that falls along a straight line in the sheet's glow, and a brightener bleaches with use, so a sheet's glow falls over its life. The prediction was that as the premium sheet's brightener bleaches, every pigment's cancelling strength rises back along that line, and that the fresh sheet's ink stays within two degrees until half the brightener is gone. Both hold. Bleached by a quarter, a half and three quarters, the premium sheet asks for strengths within 0.015 of the census line at its glow, always on or just below it; the fresh premium ink errs by 1.75, 1.80 and 2.35 degrees at worst. But the office sheet's ink, set for a glow the premium sheet passes through on its way down, keeps the bleaching sheet within 1.4 degrees at every stage after the first. An ink set for the sheet's middle age outlasts one set for its first day.

brain · Appearance The census line is a chord across a curve. For four pigments, the cancelling strength less the census line's at each sheet's glow — the light, office and premium sheets and the three bleached and yellowed premium sheets — in order of glow. The light and premium sheets sit above their own line and the office sheet under it, the orange by −0.0161, deeper than any bleached sheet: the line through the three census sheets is a chord across a sagging curve, and the bleached sheets sag beneath it as the office sheet does.

A yellowing base leaves the ink where the glow put it

A light ink cancels a pale tint's residual hue turn on brightened paper at one strength for each pigment, and as a premium sheet's brightener bleaches that strength rises back along the straight line in glow through three census sheets — a shade under it, by up to 0.013. Real photo-ageing yellows the base paper as well, and the prediction was that a base yellowed in step lifts the strengths onto the line within 0.01 and that the office sheet's ink still holds every residue within one and a half degrees. The ink holds, at 1.38°, 1.13° and 1.38°. The strengths do not lift: no pigment's moves by more than 0.0023, and its gap under the line by more than 0.0006. The yellowing raises the sheet's b* by 0.31 at most while the bleaching raises it by five. And the gap was never the base's: the office sheet itself sits 0.016 under the line, deeper than any bleached sheet. The line is a chord across a sagging curve.

brain · Appearance Every stock's ink lies on the premium stock's curve. Five pigments' cancelling strengths at a ten-per-cent target against the sheet's glow: the premium stock at eleven brightener loadings from a tenth of its own to all of it, the light, office and premium census sheets, and the premium stock bleached until its glow equals the office's and the light's. Every census sheet lies on the premium stock's curve, and the bleached premium sheets on the census sheets — the orange at 0.5581 and 0.6461 against 0.5578 and 0.6456.

The glow alone sets the light ink

A light ink cancels a pale tint's residual hue turn on brightened paper at one strength for each pigment, and that strength falls with the share of the sheet's luminance that is glow — along a curve, not the straight line through three census stocks, which runs as much as 0.016 above it. The prediction was that the strength is one curve in the glow whatever the stock: that a premium sheet bleached until its glow equals the office sheet's, or the light sheet's, needs that sheet's ink within 0.003 for every pigment. It needs it within 0.0007, though the two papers differ in base, in whiteness and in how much of the brightener their ink shields. Traced across eleven loadings of the premium stock, the curve runs through every census sheet within 0.003, sags under every chord, and falls five to nine times as steeply on a dim sheet as on a bright one for the orange, red and violet.

brain · Appearance A longer glow moves the cool inks; a shorter one moves them all. For each pigment on the premium stock at the office sheet's loading, the change in its cancelling strength at a ten-per-cent target when the brightener's emission moves from 435 nm to 450 and to 420, the same photons absorbed and emitted. At 450 nm the blue moves by +0.176 and the violet by −0.058, the orange by +0.0011; at 420 nm the orange by +0.038 and the violet by +0.077.

The glow's colour sets the blue ink and spares the orange

A light ink printed on brightened paper turns in hue, because the paper's glow passes through the ink's open area differently from the ink's own film, and a cancelling strength undoes the turn. Every sheet so far glowed with one brightener, and its ink was set by the glow's amount alone. The prediction was that a brightener emitting fifteen nanometres longer, nearer the blue and violet inks' hues, moves their strengths by more than a hundredth and the orange's and red's by under a fifth of that. It does: the blue's strength rises from 0.81 to 0.98, because a glow at the blue's own hue barely turns a blue tint, the violet's falls by 0.06, and the orange moves by a thousandth though the glow's share of the sheet's luminance nearly doubles. A brightener emitting fifteen nanometres shorter moves every ink, the orange by 0.04, and no curve in the glow's luminance reads any of them.

brain · Appearance The glow's pull reads every ink its luminance cannot. For each pigment, the largest miss over the thirty sheets, each left out, of lines in the glow's share of luminance, the share and the chromaticity y, the pull's Oklab a and b, and the pull with its squares and product. The last misses by at most 0.0139; the share alone by up to 0.249, the blue's.

The glow's pull on the white sets every ink

A light ink on brightened paper is diluted to cancel the hue turn the paper's glow gives its tints, and on sheets that all glow with one brightener its strength is a single curve in the glow's share of luminance. Move the brightener's emission and that curve fails by up to 0.21. The prediction was that two numbers — the share and the glow's chromaticity — read every ink within a hundredth. Across thirty sheets, eight of them a grid of emission peaks from 420 to 455 nm, they miss by up to 0.07, and the share alone misses the blue by a quarter. The two numbers that work are the glow's pull: how far, in Oklab, it moves the paper's own reflection to the white an adapted reader sees. Read with their squares, they set every ink within 0.014 — and the warm inks need least strength just short of where that pull is strongest.

brain · Appearance

Named alongside it

The objects these essays reach for when they reach for this one.

FluorescenceUltravioletChromatic adaptationHalftonePaper whiteRadiance factorHueIlluminantMeasurement conditionAssertionThe Donaldson matrixReflectance

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