Colour Science & Perception
what the eye settles, and what it cannot
Concept

Fluorescence — where it appears

A material absorbing light at one wavelength and re-emitting it at a longer one, so what leaves a surface never arrived there. It breaks the assumption a reflectance is built on, which is why a fluorescent sample has a matrix rather than a curve.

Named by 19 essays across 8 fields — each of them below, with the objects they name alongside it.

triphosphor fluorescent — three narrow phosphors plus the mercury lines, and the white it produces. The spectral power distribution of a triphosphor source, normalised to its own peak, and the colour a perfect white reflector takes under it: chromaticity (0.3379, 0.3389), correlated colour temperature 5258 K at Duv -0.0035. The white looks ordinary. The spectrum producing it does not.

A lamp is not a blackbody

A fluorescent tube puts a third of its light into four mercury lines. A white LED is a blue spike with a hole beside it. Both are sold by a colour temperature, and a colour temperature says nothing about either.

light · Light A sample with two reflectance curves, and neither below one. The apparent reflectance of an optically brightened sample, measured under D65 and A. It exceeds 1 — the shaded band — which no reflector can do: more light leaves at these wavelengths than arrives at them, because the sample absorbs in the violet and re-emits in the blue. And the two curves differ, so the sample has no single reflectance to store. The effect drawn here is a floor: most of the excitation band lies below 380 nm, outside the range computed here.

Some paper is brighter than white

The reflectance model assumes light leaving at a wavelength arrived at that wavelength. A fluorescent sample breaks the assumption, has no reflectance curve at all, and is in almost every sheet of white paper sold.

light · Light A sample with two reflectance curves, and neither below one. The apparent reflectance of an optically brightened sample, measured under D65 and A. It exceeds 1 — the shaded band — which no reflector can do: more light leaves at these wavelengths than arrives at them, because the sample absorbs in the violet and re-emits in the blue. And the two curves differ, so the sample has no single reflectance to store. The effect drawn here is a floor: most of the excitation band lies below 380 nm, outside the range computed here.

A surface that is not a multiplication

Every argument here about what light does to a surface begins by multiplying two spectra together. A surface with a brightener in it takes light at one wavelength and returns it at another, so it is a full operator rather than a diagonal one — and it does not have a reflectance at all.

scene · Scene Six functions of wavelength, and the six different places they stop. Every table this collection integrates against, drawn over the range the body that published it defined it on. The scale is logarithmic so that the ultraviolet and the near infrared both fit. The bottom row is the range used here before the infrared band was added, and it is the intersection of the two rows that matter for an eye looking at a reflector — which is the right answer only while everything in the integral is being multiplied together. The daylight basis runs 80 nanometres further down than that intersection, and it was published that way because the ultraviolet in daylight is what makes a brightened sheet of paper glow. The analytic row is drawn to the edge of the plot because it has no edge: Planck's law is a formula and is exact at every wavelength, which is why illuminant A needs no table at all.

The tables do not stop together

This collection integrates from 380 to 780 nanometres, and decided once, in writing, that the range could not honestly be widened. The argument was correct at the long end and wrong at the short one — the CIE publishes the daylight basis from 300 nanometres, and publishes it from there for exactly the reason it matters.

light · Light A fluorescent sample is a matrix, and a reflectance is only its diagonal. The Donaldson matrix of a brightened sheet: how much light leaves at each wavelength for light arriving at each wavelength. A reflecting surface has entries on the diagonal and nowhere else, which is exactly the statement that light leaving at 440 nanometres arrived at 440. The block off the diagonal is the fluorophore — it takes light between about 305 and 420 nanometres and returns it between 400 and 500, wherever in that band it was absorbed, which is why the block is a rectangle rather than a smear along the diagonal. A spectrophotometer that reports a reflectance is reporting the diagonal and folding the block into it at whatever weight its own lamp happened to give.

A reflectance is a diagonal

A reflecting surface returns light at the wavelength it arrived at, so its whole description is one number per wavelength. A fluorescent one returns it somewhere else, so its description is a square matrix — and the curve every instrument reports is that matrix's diagonal with the rest of it folded in at whatever weight the lamp happened to give.

light · Light A radiance factor, split into the part that was reflected and the part that was not. The two components of what leaves a heavily brightened sheet under M₁ — D50 including its ultraviolet. The lower band is the reflected component, which is what a reflectance curve means and is everything a reflectance-based model can hold. The band above it is light emitted at wavelengths it did not arrive at, and its total is decided by how much ultraviolet the source had rather than by anything about the sheet's colour. The line at one is the boundary a reflecting surface cannot cross; the sum reaches 1.21 at 430 nanometres.

The eye weights where the light is not

A brightened sheet returns a quarter more light than arrives at 430 nanometres, and it is three tenths of one per cent brighter for it. The luminous efficiency function is 0.017 there against 1.0 in the middle of the band, so the whole effect lands in the blue-yellow axis — brighter than white is a colour claim wearing a brightness word.

matching · Cones Two sheets with the same reflectance and two different colours. A brightened sheet and a dyed one built to match it under an instrument with no ultraviolet. Under that instrument the pair agrees to ΔE00 0.00, which is a rounding and is true by construction — the dyed sheet's reflectance is the curve the brightened one measured. Under an instrument that includes the ultraviolet they are 7.1 apart, and under daylight 10.6. This is not ordinary metamerism: the two sheets do not differ in reflectance anywhere the eye can see, so no change of light puts them back together and no adaptation removes the difference. One of them is a curve and the other is an operator.

Two sheets that match until the window

Ordinary metamerism is two reflectances that agree under one light and not another, and it can always be undone by putting the first light back. A dyed sheet and a brightened one have the same reflectance everywhere an eye can see, agree exactly under any lamp with no ultraviolet, and separate by ten units under daylight — and no change of light puts them back together.

scene · Scene What a sheet of glass takes out of the band a brightener eats. The transmittance of four glazings across the short-wave band, with the brightener's own absorption shaded underneath. The overlap between a curve and the shading is what the sheet behind that glass has to work with. Ordinary window glass stops below about 310 nanometres and leaves most of the band; laminated glass has a plastic interlayer that was put there to hold the sheet together in a crash and happens to absorb almost to 380; a filter sold to protect a print removes the band entirely. The curves are logistic edges at stated wavelengths rather than measurements of particular products.

The window is part of the light

A viewing condition here has always been a spectrum and a geometry. For anything fluorescent it needs a third thing — the transmittance of whatever the daylight came through — because ordinary window glass, a laminated windscreen and a museum filter remove three quite different parts of the band a brightener eats, and the sheet is a different colour behind each.

scene · Scene Six sheets, four standard measurement conditions, and every pair of them. How far apart two measurement conditions put the same sample. Darker is further. The top row has no brightener in it and every pair agrees to within a unit except the ones involving M₃, whose difference is cross-polarisation removing the interface reflection and is a change of geometry rather than of spectrum. Every row below it disagrees, and the M₁ against M₂ column reaches ΔE00 7.7 — several times any tolerance a printer would accept, on one sheet measured twice by two instruments that are both working correctly. The numbers under the columns are the means.

An instrument brings its own light

ISO 13655 names four measurement conditions and they are usually read as four degrees of care. They are not. They are four different quantities — on an unbrightened sheet all four agree to a rounding, and on a brightened one they are up to seven and a half units apart, with every instrument in calibration and every answer correct.

applied · Delivery How much of a whiteness figure is the sheet, and how much is the lamp. Each bar is how many points of CIE whiteness a stock has above an unbrightened sheet of the same base, measured with an ultraviolet-included instrument. The dark part is what survives when the ultraviolet is removed — the part that is a property of the paper. On average 82 per cent of the scale is the pale part, which is a property of the instrument's lamp. A whiteness figure without a measurement condition beside it is therefore not a measurement of a sheet; it is a measurement of a sheet and a lamp, quoted as though it were the first.

Whiteness is mostly the lamp

The CIE whiteness formula ranks white samples the way people do, which is what it was built for and is not in question. What is in question is what it is a measurement of — take the ultraviolet out of the instrument and 82 per cent of the scale collapses, because the part that separates a premium sheet from an ordinary one was contributed by the lamp.

difference · Metric The best possible 3×3, and the patches it makes worse. Each row is one patch printed on a brightened sheet, measured under both conditions. The pale bar is how far apart the two measurements are; the dark bar is what is left after the best least-squares 3×3 over the whole set has been applied. It leaves 23 per cent of the mean, and — the part a mean hides — it makes 4 patches worse than doing nothing. The solids are the ones it damages: the ink blocks the ultraviolet, so a solid barely disagrees between the two conditions and the correction has no business touching it. A matrix has no way to apply itself only where the paper is showing.

A tolerance cannot cross a condition

If two measurement conditions disagree by seven units, the obvious repair is a correction matrix fitted between them. The best least-squares 3×3 over seventeen printed patches leaves 23 per cent of the disagreement and makes five patches worse than doing nothing — because the term it is trying to remove is proportional to how much paper is showing, and no linear map on three numbers can express that.

difference · Metric Two lamps of the same colour, and one sheet that is two colours under them. The same brightened sheet under a xenon flash, the same flash behind its cover glass, and a phosphor-converted white LED of nearly the same chromaticity. Each patch is computed relative to its own lamp's white, which is what a perfect white balance does — so everything a camera can see and correct has already been removed. What is left is ΔE00 11.8 between the first and the last, against 3.2 between the two lamps themselves. The LED has no emission below 380 nanometres at all, because its pump die is at 450, so the sheet simply does not fluoresce under it and nothing in the photograph records why.

A camera cannot record the excitation

Two lamps of nearly the same chromaticity, one with ultraviolet and one with none, put a brightened sheet twelve units apart after a perfect white balance. Nothing in the camera measured the difference — the filter stack removed the band before the sensor saw it — so the correction that would fix the picture needs a quantity the file does not contain.

imaging · Capture The lamps the four conditions shine, where they differ. The short-wave half of what each measurement condition puts on the sample, plotted to 560 nanometres because past that the three are indistinguishable in shape. M₁ is D50 with its ultraviolet; M₂ is the same lamp behind a cut filter at 400 nanometres, and at 360 it is 0.0 per cent of what M₁ delivers; M₀ is a tungsten lamp, which has some ultraviolet, has less than daylight, and is not specified at all by the standard — so two M₀ instruments need not agree with each other. M₃ is not plotted because its lamp is M₂'s; what makes it a fourth condition is a polariser.

The lamp that stopped emitting ultraviolet

A blue-pumped white LED has a die at 450 nanometres and emits nothing shorter. Between about 2005 and 2020 that lamp replaced almost every other indoor source, which removed the excitation supply from a great many rooms — so brightened materials stopped glowing indoors without a single one of them being reformulated.

imaging · Capture Outside the set of colours a reflecting surface can be. How far each stock sits from the boundary of the object-colour solid, as a fraction of the bound. The line at zero is the boundary: a perfect diffuser sits exactly on it, and every reflectance ever made sits to its left. The pale marker is the sheet measured with the ultraviolet excluded and the dark one with it included. Two of the six cross the line — they are brighter, in a direction that can be written down, than any reflecting surface of their colour could be. This is a proof rather than a hull: for each sample a direction is found in which the largest value any reflectance can reach is computed exactly, and the sample exceeds it.

A white that is not a reflectance

The object-colour solid is the hardest boundary in colorimetry — the set of tristimulus values any reflecting surface can produce, with no assumption about pigments in it at all. A coated press stock under a measurement standard's own lamp sits 1.5 per cent outside it, and a heavily brightened one 4.0, and with the ultraviolet removed both come back inside.

limits · Gamut A whiteness measurement has a date on it. A brightener is consumed by the ultraviolet that makes it glow: the molecule that absorbs a photon occasionally does something other than re-emit it, and what it does is break. So the loading falls with accumulated dose and the sheet's whiteness falls with it, from W 123 to 88 — most of the way back to the unbrightened base. The fall is steepest at the start because the absorption saturates, so the first molecules lost are the ones that were doing the least work and the curve is convex from the beginning. The dose axis is in arbitrary units whose half-life is stated; what is not arbitrary is the shape.

The brightener is being used up

The molecule that absorbs an ultraviolet photon occasionally does something other than re-emit it, and what it does is break. So a sheet's whiteness has a half-life, the fall is steepest at the start, and a specification quoting a whiteness figure without a date is quoting a property of a sheet that no longer exists.

limits · Limits How blue the sheet reads, and how much of that is the room. Chroma in an appearance model, with the observer adapted to the light the sheet is under. The three markers on each row are an average, a dim and a dark surround; the open marker at the left is the same sheet with the ultraviolet removed. Every stock is close to neutral without the excitation and carries real chroma with it, at a hue of about 295 degrees — blue-violet — so the colour is the fluorescence and not the substrate. And it falls by nearly half between a bright room and a dark one, which makes how blue a sheet looks a property of where it is being looked at.

A brighter white still looks white

Colorimetry says a brightened sheet is nine units of b* from neutral, which sounds like a visible blue. An appearance model with the observer adapted to the room says it carries eleven units of chroma at a hue of 295 degrees — genuinely blue-violet — and that the number falls by nearly half between a bright room and a dark one. What it cannot say is why anybody calls the result white.

brain · Appearance Every change of light in the census, under three bases. Fourteen changes of illumination, each drawn three times: the residual left by a gain in the basis built from the dichromat confusion points, in CAT16, and in the basis that minimises the average. The ordering between the three is the same on nearly every row, and — the part an average hides — the worst row is the same row for every basis nobody fitted, which is two bounces off the same wall. The difficulty belongs to the change rather than to the choice of axes — except for the fitted winner, whose worst row is D65 to a triphosphor tube instead. What a fit buys is not a uniform improvement; it is the abandonment of the one change everybody else is beaten by.

Which changes of light pay for it

A fitted adaptation basis beats the receptors by 0.68 units on average, and an average is a poor description of what it does. On six of fourteen changes of light it is worse, and the whole of its advantage comes from four — a tungsten lamp and three coloured walls.

light · Light A radiance factor, split into the part that was reflected and the part that was not. The two components of what leaves a coated press stock under M₁ — D50 including its ultraviolet. The lower band is the reflected component, which is what a reflectance curve means and is everything a reflectance-based model can hold. The band above it is light emitted at wavelengths it did not arrive at, and its total is decided by how much ultraviolet the source had rather than by anything about the sheet's colour. The line at one is the boundary a reflecting surface cannot cross; the sum reaches 1.15 at 430 nanometres.

The ultraviolet is half the product

A fluorescent sample's departure from the reflectance model is exactly proportional to the ultraviolet the lamp carries — to twelve figures, over a range that includes zero. It is the only one of the round's four departures that really is a product of two magnitudes, and the reason is a rule about how molecules relax rather than anything about arithmetic.

light · Light Six functions of wavelength, and the six different places they stop. Every table this collection integrates against, drawn over the range the body that published it defined it on. The scale is logarithmic so that the ultraviolet and the near infrared both fit. The bottom row is the range used here before the infrared band was added, and it is the intersection of the two rows that matter for an eye looking at a reflector — which is the right answer only while everything in the integral is being multiplied together. The daylight basis runs 80 nanometres further down than that intersection, and it was published that way because the ultraviolet in daylight is what makes a brightened sheet of paper glow. The analytic row is drawn to the edge of the plot because it has no edge: Planck's law is a formula and is exact at every wavelength, which is why illuminant A needs no table at all.

The grid is a range, not an index

Three of the four departures in this round restore an argument the model dropped. The fourth does not — the 380-to-780-nanometre grid is the range of the one argument the model kept, chosen in the first weeks and never revisited. It costs 6.70 ΔE₀₀ on a coated printing paper, it is the cheapest of the four to fix, and it is the one still unfixed.

light · Light

Named alongside it

The objects these essays reach for when they reach for this one.

Optical brightenersUltravioletIlluminantMeasurement conditionRadiance factorAssertionReflectanceThe Donaldson matrixSpecificationWhitenessBispectralQuality control

All concepts