Inter-instrument agreement — where it appears
Named by 6 essays across 3 fields — each of them below, with the objects they name alongside it.
What the instrument reports
A spectrophotometer sees a sample through a slit of finite width, at a finite number of wavelengths. What it writes down is the truth convolved with its own bandpass, and nothing in the file says which values were measured and which were invented.
An aperture is a filter
A measuring aperture throws away the light that came back outside it, and the light that comes back furthest is the light at the wavelengths the sample absorbs least. So an aperture does not attenuate a translucent sample evenly — it attenuates its peaks more than its troughs, which is a filter whose transmission curve the sample itself decides.
A pair the aperture separates
Two constructed slabs with the same reflectance at every wavelength, to fifteen figures — the same colour to any observer under any light — and 6.25 ΔE₀₀ apart when measured through a four-millimetre aperture. It is a metamerism with no observer in it, no illuminant in it, and no spectral difference to construct it from.
The departures are larger than the tolerance
A delivery tolerance is written around one ΔE₀₀ and every one of this round's four departures is above it on ordinary material. A specification that names an illuminant, an observer and a tolerance, and does not name a measurement condition, an aperture and a field, has written a number that two honest laboratories can miss each other on by more than the number itself.
The instrument is one observer exactly
A spectrophotometer has no observer uncertainty. It computes through the 1931 tables to the last bit, reproducibly, forever — which is its whole value and is also why it cannot report the three colour differences of observer spread between itself and whoever is looking at the sample.
The scale hangs from one measurement
Black point compensation is a straight line between two blacks, and the destination's is a measurement of one patch at the darkest place a spectrophotometer is ever asked to read. The lightness scale's slope is 903 units per unit of luminance factor there and 43 at the paper, so a thousandth of a reflectance is worth nine tenths of a lightness unit at the black and four hundredths at the white. That one number moves a mid grey by nearly a quarter of a delivery tolerance, and no specification names it.
Named alongside it
The objects these essays reach for when they reach for this one.
Measurement conditionSpecificationApertureMeasurement uncertaintyQuality controlSpectrophotometryToleranceΔEDiffusion lengthMarginalisationSubsurface scatteringTranslucency