Concept

Inter-instrument agreement — where it appears

How closely two instruments report the same number for the same sample. It is bounded by the conditions they hold in common, so two correctly calibrated instruments differing in aperture or geometry disagree by an amount no amount of care removes.

Named by 6 essays across 3 fields — each of them below, with the objects they name alongside it.

A 20 nm bandpass, and what it does to the sample. The true reflectance, the same reflectance as a 20 nm instrument reporting every 20 nm returns it, and the slit function responsible, drawn at its own scale around 550 nm. The reconstruction is what every calculation downstream will use, and it differs from the truth by ΔE 2.97 under D65. Nothing in the file the instrument writes marks which values were measured and which were interpolated.

What the instrument reports

A spectrophotometer sees a sample through a slit of finite width, at a finite number of wavelengths. What it writes down is the truth convolved with its own bandpass, and nothing in the file says which values were measured and which were invented.

matching · Gamut
The share of a sample's reflectance an aperture recovers, by how wide it is. Six materials, and the fraction of each one's true reflectance that a measurement recovers through an aperture of the stated radius. The horizontal axis is logarithmic in millimetres; the vertical is a share, so 1.0 is the whole of it. The dashed line is a 4-millimetre radius, which is about what a hand-held spectrophotometer has. At that aperture coated paper reads 98 per cent of its own reflectance and candle wax reads 48. Every curve approaches one from below and none of them reaches it: the kernel's tail is what is being cut, and it falls as one over the aperture rather than exponentially.

An aperture is a filter

A measuring aperture throws away the light that came back outside it, and the light that comes back furthest is the light at the wavelengths the sample absorbs least. So an aperture does not attenuate a translucent sample evenly — it attenuates its peaks more than its troughs, which is a filter whose transmission curve the sample itself decides.

applied · Delivery
Two slabs with one reflectance, and two colours through an aperture. Two constructed media whose bulk reflectance agrees at every wavelength to fifteen figures, and whose diffusion lengths differ by a factor of four. The upper curve is that shared reflectance — both slabs lie on it exactly. The two patches on the right are what a 4 millimetre radius returns from each, and they are 6.3 ΔE₀₀ apart. This is a metamerism with no observer in it: the two samples are the same colour to anybody under any light, and the instrument separates them because it is measuring a kernel through a hole rather than measuring a reflectance.

A pair the aperture separates

Two constructed slabs with the same reflectance at every wavelength, to fifteen figures — the same colour to any observer under any light — and 6.25 ΔE₀₀ apart when measured through a four-millimetre aperture. It is a metamerism with no observer in it, no illuminant in it, and no spectral difference to construct it from.

matching · Gamut
Four departures from the model equation, each at an ordinary strength. What each of the four assumptions inside a colour integral costs, in ΔE₀₀, on a stated sample under a stated light. The wavelength index is a coated printing paper measured with and without the ultraviolet of D50; the range is the same paper integrated from 300 nanometres and from 380; the place index is a pigmented plastic through a four-millimetre radius; the direction index is an eggshell paint beside a window. The spread is a factor of 7.0. This is a ranking of four examples rather than of four departures — each of them can be made larger by choosing a more extreme sample, and the marble in the same collection of materials reaches 12.7 on the index that comes third here.

The departures are larger than the tolerance

A delivery tolerance is written around one ΔE₀₀ and every one of this round's four departures is above it on ordinary material. A specification that names an illuminant, an observer and a tolerance, and does not name a measurement condition, an aperture and a field, has written a number that two honest laboratories can miss each other on by more than the number itself.

difference · Metric
The conditions under which an observer's departure is exactly zero. A departure of the observer is the pairing of something belonging to the observer with something belonging to the stimulus, so emptying either factor empties the product. The axis is logarithmic in what is left when the condition is imposed. Six rows empty the stimulus's factor — a perfectly neutral sample is the same colour for every observer, at any age and any field size — and two empty the observer's, since a gain on each cone and a change of basis are both absorbed exactly. All eight are identities rather than small numbers. The last two are the same two conditions imposed in a published cone space rather than in the observer's own, and they are worth eight and thirteen units: the identity is about the eye, and the arithmetic everybody uses is in somebody else's coordinates.

The instrument is one observer exactly

A spectrophotometer has no observer uncertainty. It computes through the 1931 tables to the last bit, reproducibly, forever — which is its whole value and is also why it cannot report the three colour differences of observer spread between itself and whoever is looking at the sample.

applied · Delivery
One instrument, one uncertainty, six places on the scale. What an absolute uncertainty of 0.001 in measured reflectance is worth in lightness, at six levels from a four-colour solid to the paper. Nothing about the instrument changes between the rows: what changes is the slope of the lightness function, which is a straight line of 903 units per unit of luminance factor below a luminance of 0.0089 and a cube root above it. At the solid the uncertainty is 0.903 lightness units and at the paper 0.043 — 21 times as much, for the same measurement.

The scale hangs from one measurement

Black point compensation is a straight line between two blacks, and the destination's is a measurement of one patch at the darkest place a spectrophotometer is ever asked to read. The lightness scale's slope is 903 units per unit of luminance factor there and 43 at the paper, so a thousandth of a reflectance is worth nine tenths of a lightness unit at the black and four hundredths at the white. That one number moves a mid grey by nearly a quarter of a delivery tolerance, and no specification names it.

applied · Delivery

Named alongside it

The objects these essays reach for when they reach for this one.

Measurement conditionSpecificationApertureMeasurement uncertaintyQuality controlSpectrophotometryToleranceΔEDiffusion lengthMarginalisationSubsurface scatteringTranslucency

All concepts