Every essay — page 23
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What light is
A spectrum is a function, not a colour. Illuminants, reflectance, blackbody radiation computed from Planck's law, and what has already been discarded before the eye is reached.
A second slit buys a quarter
A line lamp wants a five-nanometre slit and a notched sample a one-nanometre slit, so an instrument with a slit for each should do much better than one with a single compromise. Over sixty-eight notches under a fluorescent tube, it does better by 28 per cent. One slit on the reflected light does fifteen times better than the best pair, and an oracle choosing the best pair for every notch is still six times worse. The error was never that the factors were flattened; it was that they were flattened separately.
The tables cannot bound what they discarded
A colour computed from a lamp's blurred table and a sample's blurred table is wrong by the covariance the two blurs threw away, and Cauchy–Schwarz bounds a covariance by two variances. With the true variances the bound always holds and sits fifteen times above the error. With variances read from the tables it fails on six of sixty-eight notches under a fluorescent tube and twenty-two under a laser projector — on the line, where the error is largest. A blurred table does not carry the width of a line, and the covariance depends on it.
A declared width buys a factor of two
A colour engine given two separately blurred spectral tables cannot bound its own error from them, and the bound that always holds — the peak declared and nothing else — sits a median 196 times above the error under a fluorescent tube. Adding one number, the width of the lamp's narrowest feature, brings that to 86. It never fails on any declaration the lamp truly meets, it fails on 47 of 68 notches on one it does not, and its rank correlation with the error it bounds is 0.27.
A narrow slit shrinks the error, not the bound
A colour engine given two separately blurred spectral tables can bound its own error if the lamp declares its narrowest feature, and under a fluorescent tube that bound sits 86 times above the error at a five-nanometre slit. Narrowing the slit was supposed to close the gap, because a comb of narrow features stops fitting in a narrow window. It does the opposite. At one nanometre the error falls 27-fold and the bound only sevenfold, so the bound is 253 times loose and certifies no notch within a colour difference. The looseness was never the comb. It is the lamp's one declared peak, charged to every window.
A narrow table can vouch for its own peaks
The bound a colour engine can put on its bandpass error is loose because a lamp declares one peak for its whole spectrum and the bound charges it to every window. A table measured through a slit about as narrow as the lamp's lines can do better: no feature of the declared width can be blurred below a computable fraction of its height, so the table's own entries cap how tall the lamp can be in each window. At one nanometre that ceiling is never below the truth and sits twice above it, where the global peak sat twenty times above. The bound halves, and for the first time it certifies notches within a colour difference. At five nanometres it buys nothing at all.
A finer grid keeps the price of separating
A sample's reflectance and a lamp's spectrum measured through separate slits can be reused under any other lamp; measured together through one slit on the reflected light, they are fifteen times more accurate and belong to that one lamp. A finer grid was expected to close the gap, because a one-nanometre table barely blurs anything. It closes most of the distance to the old answer and none of the distance to the new one. On a one-nanometre grid the best separate pair under a fluorescent tube is as good as one slit on the product used to be at five, and one slit on the product on the same fine grid is twenty-nine times better again.
A correction travels with its lines
Keeping a sample's reflectance and a lamp's spectrum as separate tables costs fifteen times the error of measuring their product under a fluorescent tube. The middle course proposed was to measure the product once under a representative tube, store the ratio of product to separable colour with the sample, and apply it under any tube. Under tubes whose lines are narrower or wider, or whose phosphors sit elsewhere, it removes nine tenths of the error. Under a tube with the same lines in a different mix it removes under two thirds, and less the further the mix moves. Under an LED or a laser it makes things worse — a white LED five times worse than no correction. A class of lamps, for this purpose, is a mix of lines.
A narrow table declares its own lines
A bound on a colour table's bandpass error needs one number from the lamp's maker: its narrowest feature, 1.2 nm for a fluorescent tube. Through a slit about as narrow as that feature, the table's entries around each line carry its width. Measured to half a per cent, a one-nanometre table's entries admit only line widths within four per cent of the truth, and a bound built on the narrowest of them is within two per cent of the bound on the maker's number. Through two nanometres the table still declares a usable width. Through three it cannot rule out a line five times narrower, and the bound it supports is the global one. The failure is as sharp as predicted, and never unsafe.
A table can refuse a pair it cannot resolve
A narrow spectral table reads each of its peaks as one line and declares the line's width from the entries round it, and the assumption under that is that every peak is a line. Split the mercury tube's yellow into the real pair at 577 and 579 nm and the table notices: through one and two nanometre slits no single line fits the entries within half a per cent, so the table refuses to read a width there. Swept apart, a pair is refused once it is split by about the grid step and admitted when it is closer — always as one wider line, up to 3.3 times too wide. Through three nanometres the pair reads as a 3.2 nm line, and a 3 nm europium band beside it reads the same.
A line's wings widen the width a table declares
A narrow table declares its lamp's narrowest line width by fitting each peak with a Gaussian, and the worry was a line whose profile is not Gaussian: a mercury line broadened by collisions has Lorentzian wings on its core, every line shares them, and a Gaussian fit can only take the wings in by widening. It does. With wings a quarter of the core's width, the table declares 1.36 nm for a 1.2 nm core — close to the winged line's own half-maximum width, 1.37. The prediction called that the unsafe direction. It is not: the ceiling and the variance the earlier bound builds on the declared width never fall below the winged lamp's own, because through a slit a winged line behaves like the wider line the table says it is.
A reversed line is read as one line
A strong mercury line in a dense discharge absorbs its own centre on the way out: at an optical depth of one its top is flat, and beyond that it dips, until at four the line is two humps with a trough eighty per cent deep between them. The prediction was that a one-nanometre table refuses such a line from a depth of about one and a two-nanometre table reads it as a Gaussian about the width of its flat top, safely. Both hold, and the second only up to a point. A two-nanometre table admits the line at every depth to four, and from three and a half the width it admits is too wide for the humps: the ceiling built on it falls eleven per cent below the line's true peak. The only line that could make a declared width unsafe was one narrower at its peak than its entries suggest — and a reversed line is exactly that.
A notch in a line is never refused
A dense discharge's green mercury line loses its centre to the atoms between the glow and the tube wall, and those atoms are cooler than the glow, so their absorption is narrower than the line it cuts. With the absorbing layer half or a third as wide as the line, a one-nanometre table still refuses the line from an optical depth of one, exactly where it refused the broad dip. A two-nanometre table never refuses it at all: to a depth of five, with ninety-eight per cent of the centre gone, one Gaussian fits its entries within a seventh of a per cent. And the ceiling built on the width it reads fails from a depth of about two and a third — a whole unit sooner than behind a column as wide as the line — and never recovers, falling to three quarters of the true peak.